On 28 September 2012 20:17, David Riley <fraveydank at gmail.com> wrote:
I was always under the impression that that sort of story was an urban
legend.
I have often boiled water in the microwave; when I had a Norwegian
fianc?e, she did not own a kettle & always boiled water in the
microwave. (Electricity is *very* cheap there, as they have lots of
hydroelectric plants.) The thing is, normally, the water just boils.
The physics isn't out of the question, I just
can't imagine
any container in a household that wouldn't provide a sufficiently
rough surface to nucleate. Surprised to hear it's a thing!
Almost any ordinary container has multiple nucleation points. Pour a
fizzy drink into any household object; every chain of bubbles rising
from the sides and bottom is coming from a nucleation
point.
In the case of water in a mug or something, it can get to a good few
degrees over 100?C (sorry, I cannot fathom Fahrenheit & have no clue
what boiling point is in it; I use SI units, like all sensible people)
and thus when you drop in a teabag or a spoonful of coffee, *FOOM*,
instant boiling and water all over the counter-top.
But getting hot enough to become superheated? That I have /never/
seen, even when someone set the timer wrong and the container boiled
dry.
Now, if it was a /sealed/ container, a reasonably strong one, able to
withstand a lot of pressure before it blew - OK.
But an open vessel? No, I don't believe it. Even scrupulously clean
laboratory glassware has lots of nucleation points; getting water to
supercool or superheat without crystallising or boiling is actually
quite hard to do. Supercooling is easier but still nontrivial; it can
happen by accident, but rarely.
Either way, the further the temperature goes past the normal
phase-change temperature, the smaller the imperfection needed to start
the transition.
--
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