I just looked,
and V.25 explicitly refers to the V.24 pinout. V.25 (and
V.25bis and V.25ter) only specify procedures user over the v.24 circuit in
automatic dialling scenarios (when to raise/lower which signals and a
DTE-DCE command/response format) V.25ter is the familiar AT command set.
Hmmm....
I have an instrument here (an HPIB extender) with 2 DB25's on the back.
One is marked 'RS232 V24' and is clearly a normal-ish serial port to
connect to a modem. The other is for an autodialer and is marked 'RS336
V25' (I think that's the right RS number, maybe RS339). I don't think
It's actually RS366 (that will teach me to post without the device in
front of me), which seems to be a standard for the interface to an
autodialer.
From waht I can determine, it uses 'RS232
levels', and transfers a nybble
at a time in parallel to dial a phone number
(digits are encoded in BCD,
the other 6 combinations are used for things like #, * I guess). I found
a pinout for that on the web, and amazingly the pins used in the HPIB
extender would agree with that :-)
-tony