A great resource is the Amateur Radio Relay League (ARRL).
http://www.arrl.org They have tons of information and resources,
including downloadable question/test pools, sample tests (
http://www.arrl.org/question-pools ), and information on where and
when the nearest exams will be held. Most larger cities have a club
as well (such as the Wichita Amateur Radio Club in my area) which can
help you with testing and even with getting your shack set up. Some of
the clubs in NY can be found here:
http://www.gunkswriter.com/h/omarc/links-body.html
Good luck with your new undertaking!
--Shaun, N0WHG