On 27 Apr 2011 at 20:58, Tony Duell wrote:
The Nodon valve? I've read about them, never
had the urge to kmake
one. I thought hte electrolyte was more commonly ammonium phosphat, or
at least I think that's what the book I've read reocmmends.
A wide range of electrolytes can be used.. Sodium phosphate,
carbonate, bicarbonate, ammonium sulfate, etc. In the US,
bicarbonate of soda was most frequently employed by amateurs because
it was cheap and easy to obtain.
A book entitled 'small AC transformers' [1] gives the following
instructions for making chemical rectifiers.
"The satisfactory operation of this type of rectifier largely depends on
the condiiton of the electrolyte., and in its preparation the following
directions should be attended to. Make a saturated solution of commercial
phospate of ammonia in warm water , stiring thoroughly until disolved,
and when cold test with a slip of blue litmus paper. Probably it will be
found to be strongly acid and the paper will turn red. Drop in a little
liquid ammonia, stirring well until the precipuiate it forms is again
disolved, and take another litmus test. When the paper ceases to redden
the acid will bave been neutralised and the solution ready for use. Fill
each jar two-thirds full and then float half an inch of paraffin oil on
top of the solution. This prevents evaporation and creepage of the salds.
In course fo time the soltion will become acid again and then requires
neutralising with ammonia as before. Set up in this way the chemical
rectifier will give exceedingly good service; without these precaustions
it is a messy appliance and likely to earn a bad name for itself. Keep
it as cool as possible since the rectifying action falls off as the
temperature rises'
That's for a rectifier with aluminium and lead electrodes, BTW
[1] YEs, I know all staticve transformers only work on AC. At the time
this book was written, the term 'DC transformer' was used for a
motor-generator set.
-tony